Alcohol Phenol and Ether questions in NEET focus on the structure, properties, and reactions of these organic compounds. Key areas include identification of functional groups, acidity and reactivity differences, mechanisms such as substitution, dehydration, and electrophilic aromatic substitutions, and understanding the IUPAC nomenclature, resonance, and function of electron-donating/withdrawing groups. These questions test knowledge of practical consequences and practical applications, making them crucial for building a solid foundation in organic chemistry for the NEET exam.
Alcohols Phenols and Ethers is a major in organic chemistry for NEET aspirants. Questions on these compounds test students’ understanding of functional groups, chemical properties, and mechanisms of action. Alcohols have the characteristic -OH functional group, phenols have an -OH group attached to the aromatic ring, while ethers show -O- bonds between the two carbon chains NEET questions usually focus on how these compounds behave, the oxidation, substitution, . and intermolecular interactions. Knowledge of these topics is important, as it reinforces broad concepts such as acidity, basicity, and resonance effects in organic molecules. Proper preparation for this section can help students strengthen their foundation in organic chemistry and score better in NEET competitive environment.
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Alcohol Phenol and Ether NEET Questions with Answer | Click |
Topic | Content |
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Classification | Primary Alcohols: -OH group attached to a primary carbon atom (R-CH2-OH) Secondary Alcohols: -OH group attached to a secondary carbon atom (R2CH-OH) Tertiary Alcohols: -OH group attached to a tertiary carbon atom (R3C-OH) |
Nomenclature and Structure | IUPAC Nomenclature: Use the suffix “-ol” to indicate the presence of the -OH group. Common Names: Use the name of the alkyl group followed by “alcohol.” Structure: The -OH group is polar due to the electronegativity difference between oxygen and hydrogen. |
Physical Properties | Boiling Point: Higher boiling points than alkanes due to hydrogen bonding. Solubility: Lower alcohols are soluble in water due to hydrogen bonding. Density: Density increases with increasing molecular weight. |
Chemical Properties | Acidity: Weakly acidic due to the polarization of the O-H bond. Oxidation: Primary alcohols can be oxidized to aldehydes or carboxylic acids. Secondary alcohols can be oxidized to ketones. Tertiary alcohols are resistant to oxidation. Dehydration: Alcohols can be dehydrated to form alkenes in the presence of an acid catalyst. Esterification: Alcohols react with carboxylic acids to form esters in the presence of an acid catalyst. Reaction with Acids and Bases: Alcohols can react with acids to form alkyl halides and with bases to form alkoxides. |
Preparation Methods | Hydration of Alkenes: Alkenes react with water in the presence of an acid catalyst to form alcohols. Hydroboration-Oxidation of Alkenes: Alkenes react with diborane followed by oxidation with hydrogen peroxide to form alcohols. Reduction of Carbonyl Compounds: Aldehydes and ketones can be reduced to primary and secondary alcohols, respectively, using reducing agents like LiAlH4 or NaBH4. |
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Structure and Classification | Structure: Phenols contain a hydroxyl group (-OH) directly attached to an aromatic ring. Classification: Based on the number of hydroxyl groups: monohydric, dihydric, trihydric, etc. |
Nomenclature and Types | IUPAC Nomenclature: Use the suffix “-ol” to indicate the presence of the -OH group. Common Names: Phenol, cresol, catechol, resorcinol, hydroquinone |
Physical Properties | Boiling Point: Higher boiling points than alcohols due to stronger hydrogen bonding. Solubility: Slightly soluble in water due to hydrogen bonding. Acidity: More acidic than alcohols due to resonance stabilization of the phenoxide ion. |
Chemical Properties | Electrophilic Substitution Reactions Halogenation: Phenols undergo electrophilic substitution with halogens to form halogenated phenols. Nitration: Phenols undergo electrophilic substitution with nitric acid to form nitrophenols. Sulfonation: Phenols undergo electrophilic substitution with concentrated sulfuric acid to form phenolsulfonic acids. Oxidation Oxidation by Mild Oxidizing Agents: Phenols are oxidized to quinones. Oxidation by Strong Oxidizing Agents: Phenols are oxidized to carboxylic acids. Reaction with Bases: Phenols react with strong bases like NaOH to form phenoxide ions. |
Preparation Methods | From Cumene: Cumene is oxidized to cumene hydroperoxide, which is then treated with acid to form phenol and acetone. From Benzene Sulfonic Acid: Benzene sulfonic acid is fused with sodium hydroxide to form sodium phenoxide, which is then acidified to form phenol. From Diazonium Salts: Diazonium salts are treated with water to form phenols. |
Topic | Content |
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Classification | Simple Ethers: Both alkyl groups attached to the oxygen atom are the same. (R-O-R) Mixed Ethers: The two alkyl groups attached to the oxygen atom are different. (R-O-R’) |
Nomenclature and Structure | IUPAC Nomenclature: Name the two alkyl groups followed by “ether.” Common Names: Use the name of the alkyl groups followed by “ether.” Structure: The oxygen atom is sp3 hybridized and has two lone pairs of electrons. |
Physical Properties | Boiling Point: Lower boiling points than alcohols of comparable molecular weight due to the absence of hydrogen bonding. Solubility: Slightly soluble in water. Density: Lower density than water. |
Chemical Properties | Relative Inertness: Ethers are relatively inert compounds. Cleavage by Acids: Ethers can be cleaved by strong acids like HI or HBr to form alkyl halides and alcohols. Reaction with Halides: Ethers can react with halides to form alkyl halides. |
Preparation Methods | Williamson Ether Synthesis: Alkoxides react with alkyl halides to form ethers. Dehydration of Alcohols: Alcohols can be dehydrated to form ethers in the presence of an acid catalyst. |
General components: R-OH
Hydroxyl organization (-OH) is attached to an alkyl group (R).
General components: Ar-OH
Hydroxyl organization (-OH) is at once attached to an aromatic ring (Ar).
General method: R-O-R’
Oxygen atom is linked to 2 alkyl or aryl businesses (R and R’).
Property | Alcohols | Phenols | Ethers |
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Functional Group | -OH connected to alkyl organization | -OH attached to aryl institution | -O- linking two alkyl/aryl businesses |
Acidity | Weakly acidic | More acidic than alcohols | Neutral |
Boiling Point | Higher because of H-bonding | Higher due to H-bonding | Lower |
Solubility in Water | Lower alcohols soluble | Lower phenols soluble | Generally much less soluble |
Reactivity | More reactive | More reactive than ethers | Less reactive |
Uses | Solvents, fuels, medicines | Disinfectants, prescription drugs | Solvents, anesthetics |
Question Type | Example Questions | Detailed Solutions | ||||||||||
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Multiple Choice Questions (MCQs) | 1. Which of the following is a correct statement about DNA replication? * A. It is a semi-conservative process. * B. It occurs in the S-phase of the cell cycle. * C. DNA polymerase is the enzyme involved. * D. All of the above. | [Detailed explanation of DNA replication, including the role of DNA polymerase and the semi-conservative nature of the process.] | ||||||||||
2. Which of the following hormones is responsible for the “fight or flight” response? * A. Insulin * B. Adrenaline * C. Thyroxine * D. Growth hormone | [Detailed explanation of the endocrine system, focusing on the role of adrenaline in the stress response.] | |||||||||||
Assertion-Reason Questions | 3. Assertion: Photosynthesis is an anabolic process. Reason: Photosynthesis involves the synthesis of glucose from carbon dioxide and water. | [Explanation of anabolism and catabolism, and the role of photosynthesis in energy conversion.] | ||||||||||
4. Assertion: Mitochondria are the powerhouse of the cell. Reason: Mitochondria are the site of cellular respiration, where ATP is produced. | [Detailed explanation of cellular respiration and the role of mitochondria in energy production.] | |||||||||||
Matching Type Questions | 5. Match the following:
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6. Match the following:
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Practice Questions with Detailed Solutions | 7. A ball is thrown vertically upwards with an initial velocity of 20 m/s. Find the maximum height reached by the ball. (Take g = 10 m/s²) | [Detailed solution using equations of motion, explaining each step.] | ||||||||||
8. Calculate the pH of a 0.1 M solution of acetic acid (Ka = 1.8 × 10⁻⁵). | [Detailed solution using the Henderson-Hasselbalch equation, explaining the concept of acid dissociation constant.] |
Ans: Mostly conceptual questions on structure, reactions, residences, and IUPAC naming, as well as software-primarily based questions.
Ans: Usually, 1-2 questions are requested from this chapter in NEET.
Ans: Focus on nomenclature, physical properties, training strategies, reactions, and differences in acidity/basicity.
Ans: Understand response mechanisms, exercise questions, and memorize key reactions and their conditions.
Ans: Important reactions consist of Williamson synthesis, Kolbe’s response, Reimer-Tiemann reaction, and oxidation reactions.
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